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・ Trifurcula headleyella
・ Trifurcula helladica
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・ Trifluoromethanesulfonic acid
・ Trifluoromethanesulfonic anhydride
Trifluoromethanesulfonyl azide
・ Trifluoromethyl
・ Trifluoromethyl hypofluorite
・ Trifluoromethyl sulphur pentafluoride
・ Trifluoromethylaminoindane
・ Trifluoromethylation
・ Trifluoromethylisocyanide
・ Trifluoromethylphenylpiperazine
・ Trifluoromethylsulfonyl
・ Trifluoromethyltrimethylsilane
・ Trifluorooxonium
・ Trifluorotoluene
・ Trifluperidol
・ Triflupromazine
・ Trifluralin


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Trifluoromethanesulfonyl azide : ウィキペディア英語版
Trifluoromethanesulfonyl azide

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Trifluoromethanesulfonyl azide or triflyl azide is an organic azide used as a reagent in organic synthesis.
==Preparation==
Trifluoromethanesulfonyl azide is not commercially available. It is prepared before use by reacting trifluoromethanesulfonic anhydride with sodium azide, traditionally in dichloromethane. However, use of dichloromethane should be avoided because sodium azide is known to generate highly explosive azido-chloromethane and diazidomethane in situ by nucleophilic substitution on dichloromethane.〔Cavender, C. J.; Shiner, V. J., Jr. J. Org. Chem. (1972), 37, 3567.〕 Moreover, the volatility of dichloromethane is a liability, as unsolvated triflyl azide is a detonation hazard.〔 The reaction may also be carried out in toluene,〔Titz, A.; Radic, Z.; Schwardt, O.; Ernst, B. Tetrahedron Lett. (2006), 47, 2383.〕 acetonitrile, or pyridine.
: Tf2O + NaN3 → TfN3 + NaOTf (Tf = CF3SO2)
The trifluoromethanesulfonic anhydride starting material is rather expensive, and the product is explosive, and does not store well. As a result, imidazole-1-sulfonyl azide has been developed as an alternative.

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